Paper on Synthesis of NaYF4 Nanowires Published in Chemistry of Materials

Our paper on the synthesis of sodium yttrium fluoride (NaYF4) nanowires has just been published in Chemistry of Materials! Led by Alex Bard at the University of Washington, this paper describes multi-modal analysis of crystal growth mechanisms in this system, which is of importance for a range of applications in chemistry, materials science, and biology.

From the abstract:

Sodium yttrium fluoride (NaYF4) is an important upconverting material with many potential uses in chemistry, materials science, and biology, which can be synthesized hydrothermally in both cubic (α) and hexagonal (β) crystallographic polymorphs. Understanding the mechanisms underlying the phase conversion between the cubic and hexagonal polymorphs is of great interest to help inform future efforts to synthesize atomically-precise quantum materials with well-defined sizes and morphologies. In this work, we use a combination of analytical transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), powder X-ray diffraction (XRD), in situ liquid cell TEM, atom probe tomography (APT), and extended x-ray absorption fine structure (EXAFS) measurements to show that the hexagonal NaYF4 nanowires form through a non-classical crystal growth mechanism involving the formation and subsequent oriented attachment of mesocrystals consisting of cubic (α) phase units. EXAFS spectroscopy also suggests that substitutional Yb3+ point defects within NaYF4 are distributed evenly throughout the crystal lattice without clustering, and also that they may exhibit selective substitution into one of the two possible trivalent yttrium sites in the unit cell in hydrothermally synthesized β-NaYF4.

To view the manuscript, visit: https://doi.org/10.1021/acs.chemmater.9b04076

To download the manuscript directly, click here.